JEE Main levelNumerical answerDifficulty 2 of 3ro176
Benzoic acid (molar mass 122gmol−1) is converted by Birch reduction into cyclohexa-2,5-diene-1-carboxylic acid (molar mass 124gmol−1). Starting from 12.2g of benzoic acid and obtaining an isolated yield of 80%, what mass of the diene acid is obtained? Give the answer in grams to two decimal places.
Numerical answer type, answer in g, tolerance 0.05.
Answer: 9.92 g
Moles of benzoic acid are 12.2/122=0.100. The reaction is one-to-one, so the theoretical yield is 0.100×124=12.4g. At 80% yield the mass is 12.4×0.80=9.92g.