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JEE Main levelSingle correct optionDifficulty 2 of 3ro152

Methyl 4-nitrobenzoate, methyl benzoate and methyl 4-methoxybenzoate are hydrolysed with dilute aqueous NaOH under identical conditions. The rate is greatest for

  1. Aall three have equal rates
  2. Bmethyl 4-nitrobenzoate
  3. Cmethyl benzoate
  4. Dmethyl 4-methoxybenzoate

Answer: B

The rate-determining step is attack of on the carbonyl carbon, which is favoured by electron-withdrawing groups. The 4-nitro group makes the carbonyl carbon more electrophilic, whereas 4-methoxy donates electrons by resonance. The order is nitro H methoxy.
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