MolSynapsequestion bank
MolSynapse / Question bank / Reduction, Oxidation and Hydrolysis in Organic Chemistry / Oxidation with KMnO4, K2Cr2O7, PCC, Jones
JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ro144

Which of the following give benzoic acid on heating with hot alkaline followed by acidification?

  1. AToluene
  2. BBenzyl alcohol
  3. CEthylbenzene
  4. Dtert-Butylbenzene

Answer: A, B, C

Toluene, ethylbenzene and benzyl alcohol all carry a benzylic carbon bearing hydrogen, which is oxidised to the carboxyl group (the extra carbon of ethylbenzene is lost as ). tert-Butylbenzene has no benzylic hydrogen and is unchanged.
Practice Reduction, Oxidation and Hydrolysis in Organic Chemistry More on Oxidation with KMnO4, K2Cr2O7, PCC, Jones

More questions on Oxidation with KMnO4, K2Cr2O7, PCC, Jones