JEE Main levelNumerical answerDifficulty 2 of 3ro122
1.00 mol of 4-nitrocinnamaldehyde, OX2N−CX6HX4−CH=CH−CHO (nitro group on the ring para to the side chain), is hydrogenated with excess HX2 over Pd-C at 1 atm and room temperature until uptake stops. Assume the benzene ring is not reduced, the nitro group goes to NHX2, the aldehyde goes to CHX2OH and no hydrogenolysis occurs. How many moles of HX2 are absorbed? (Give an integer.)
Numerical answer type, tolerance 0.5.
Answer: 5
NOX2NHX2 needs 3 HX2, the C=C needs 1 and CHOCHX2OH needs 1. Total =3+1+1=5 mol of HX2, giving 3-(4-aminophenyl)propan-1-ol.