JEE Main levelSingle correct optionDifficulty 2 of 3ro118
Benzyl acetate, CHX3COOCHX2CX6HX5, is stirred under HX2 (1 atm) with Pd-C at room temperature until reaction stops. The products are
Abenzoic acid and ethanol
Bbenzyl alcohol and ethanal
Cethanoic acid and toluene
Dethyl ethanoate and benzene
Answer: C
Benzylic C-O bonds undergo hydrogenolysis over Pd-C, while the aromatic ring is untouched. Cleavage of the CX6HX5CHX2−O bond gives toluene and ethanoic acid.