JEE Main levelSingle correct optionDifficulty 2 of 3ro082
Open-chain D-fructose, HOCHX2−CO−(CHOH)X3−CHX2OH, is treated with excess HIOX4. The moles of HIOX4 consumed and the products per mole of fructose are
A5 mol; 2 HCHO, 3 HCOOH, 1 COX2
B5 mol; 1 HCHO, 5 HCOOH
C5 mol; 1 HCHO, 4 HCOOH, 1 COX2
D6 mol; 2 HCHO, 3 HCOOH, 1 COX2
Answer: A
All six carbons are oxygenated, so 5 C-C bonds are cleaved and 5 mol of HIOX4 are used. The two terminal CHX2OH groups give 2 HCHO, the three CHOH carbons give 3 HCOOH, and the ketone carbon, cleaved on both sides, becomes COX2.