JEE Main levelSingle correct optionDifficulty 2 of 3ro081
Benzoin, CX6HX5−CH(OH)−CO−CX6HX5, is treated with one equivalent of HIOX4. The products are
Atwo molecules of benzaldehyde
Bbenzaldehyde and benzoic acid
Cbenzil
Dtwo molecules of benzoic acid
Answer: B
An alpha-hydroxy ketone is cleaved between the carbinol carbon and the carbonyl carbon. The CHOH end gives CX6HX5CHO and the C=O end gives CX6HX5COOH. One mole of HIOX4 is consumed.