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JEE Advanced levelSingle correct optionDifficulty 3 of 3ro050

1-Bromobutane is treated with KCN to give X; X is heated under reflux with dilute to give Y; Y is reduced with followed by aqueous work-up to give Z. Z is

  1. Abutan-1-ol
  2. Bpentan-1-amine
  3. Cpentanal
  4. Dpentan-1-ol

Answer: D

X is pentanenitrile (one carbon added), Y is pentanoic acid (acid hydrolysis of the nitrile), and Z is since reduces a carboxylic acid to a primary alcohol.
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