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Reduction, Oxidation and Hydrolysis in Organic Chemistry
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Dissolving metal reductions (Birch, Na/NH3)
NEET level
Single correct option
Difficulty 1 of 3
ro020
Reduction of but-2-yne with sodium in liquid ammonia gives
A
cis-but-2-ene
B
butane
C
but-1-ene
D
trans-but-2-ene
Answer: D
Dissolving-metal reduction of an internal alkyne proceeds through a trans vinyl radical/anion and gives the trans (E) alkene.
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