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JEE Main levelSingle correct optionDifficulty 2 of 3ro007

2,2-Dimethyloxirane (isobutylene oxide) is treated with in ether and then with dilute acid. The major product is

  1. A2-methylpropan-2-ol
  2. B2-methylpropan-1-ol
  3. C2-methylpropane-1,2-diol
  4. Dpropan-2-ol

Answer: A

Hydride attacks the less hindered epoxide carbon (the ), SN2 style. The oxygen stays on the more substituted carbon, giving after work-up: 2-methylpropan-2-ol.
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