JEE Main levelSingle correct optionDifficulty 2 of 3ro007
2,2-Dimethyloxirane (isobutylene oxide) is treated with LiAlHX4 in ether and then with dilute acid. The major product is
A2-methylpropan-2-ol
B2-methylpropan-1-ol
C2-methylpropane-1,2-diol
Dpropan-2-ol
Answer: A
Hydride attacks the less hindered epoxide carbon (the CHX2), SN2 style. The oxygen stays on the more substituted carbon, giving (CHX3)X3C−OH after work-up: 2-methylpropan-2-ol.