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JEE Main levelOne or more correct optionsDifficulty 2 of 3rx195

Which of the following statements about permanganate titrations in the laboratory are correct?

  1. A acts as its own indicator, the end point being the first permanent pale pink colour
  2. BDilute is the suitable acid for providing the acidic medium
  3. CDilute is unsuitable because is oxidised by , causing an error
  4. DIn neutral medium the n-factor of is 5

Answer: A, B, C

Permanganate is intensely coloured, so a slight excess gives a permanent pink end point. Dilute is inert towards it, whereas is oxidised (and is itself an oxidant). In neutral medium Mn goes from +7 to +4, so n = 3, not 5. Hence A, B and C are correct.
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