JEE Advanced levelSingle correct optionDifficulty 3 of 3rx149
Use O = 16 and molar volume 22.4L/mol at STP. Ammonia reduces hot copper(II) oxide: 2NHX3+3CuONX2+3Cu+3HX2O. When 4.48L of NHX3 (at STP) is passed completely over excess CuO, the loss in mass of the solid in the tube is:
A3.2 g
B19.05 g
C5.4 g
D4.8 g
Answer: D
n(NHX3)=4.48/22.4=0.2. CuO reacted =0.2×3/2=0.3 mol, each losing one O atom to the gas phase as water. Mass lost =0.3×16=4.8g (the solid becomes Cu).