JEE Advanced levelNumerical answerDifficulty 3 of 3rx104
In basic medium Cr(OH)X3 is oxidised by chlorate: Cr(OH)X3+ClOX3X−+OHX−CrOX4X2−+ClX−+HX2O. In the balanced equation (smallest whole numbers) find the sum of the coefficients of OHX− and HX2O. Give the answer as an integer.
Numerical answer type, tolerance 0.1.
Answer: 9
Cr loses 3 electrons (+3 to +6) and Cl gains 6 (+5 to -1), so Cr(OH)X3 : ClOX3X− = 2 : 1. Charge balance needs 4 OHX− on the left, and O/H balance gives 5 HX2O: 2Cr(OH)X3+ClOX3X−+4OHX−2CrOX4X2−+ClX−+5HX2O. Sum of coefficients of OHX− and HX2O = 4 + 5 = 9.