JEE Advanced levelNumerical answerDifficulty 3 of 3rx044
Wustite has the non-stoichiometric composition FeX0.93O, with iron present only as Fe2+ and Fe3+. Find the percentage of iron atoms present as Fe3+. Give the nearest integer.
Numerical answer type, answer in %, tolerance 0.5.
Answer: 15 %
Let the fraction of Fe3+ be f. Charge balance: 0.93(2+f)=2, so f=2/0.93−2=0.1505. That is 15.05%, i.e. 15 to the nearest integer.