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Critical constants and liquefaction
JEE Main level
Numerical answer
Difficulty 2 of 3
rg202
A van der Waals gas has
T
c
=
304
K
and
V
c
=
0.128
L
mo
l
−
1
. Using
Z
c
=
3/8
and
R
=
0.0821
L
atm
K
−
1
mo
l
−
1
, its critical pressure in atm (one decimal) is
Numerical answer type, answer in atm, tolerance 0.3.
Answer: 73.1 atm
P
c
=
8
V
c
3
R
T
c
=
8
×
0.128
3
×
0.0821
×
304
=
1.024
74.875
=
73.12
atm
, i.e.
73.1
atm
.
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