JEE Advanced levelNumerical answerDifficulty 3 of 3rg195
The inversion temperature of a gas is 1030K and its van der Waals constant a=0.364Pam6mol−2. Using Ti=2a/Rb and R=8.314JK−1mol−1, the value of b in cm3mol−1 (one decimal) is
Numerical answer type, answer in cm^3/mol, tolerance 0.2.
Answer: 85 cm^3/mol
b=RTi2a=8.314×10302×0.364=8563.40.728=8.5013e−05m3mol−1=85.01cm3mol−1, i.e. 85.0cm3mol−1.