JEE Main levelSingle correct optionDifficulty 2 of 3rg183
Among the following, the gas expected to have the smallest value of the van der Waals constant a is
ANe
BAr
CKr
DXe
Answer: A
For noble gases attraction arises only from dispersion forces, which increase with polarisability and hence with size. Neon is the smallest, so its a (0.21L2atmmol−2) is the least; xenon has the largest (4.19).