JEE Main levelNumerical answerDifficulty 2 of 3rg182
0.500mol of a gas with a=5.46L2atmmol−2 and b=0.0305Lmol−1 is confined to 0.400L at 350K. The van der Waals pressure in atm (two decimals, R=0.0821LatmK−1mol−1) is
Numerical answer type, answer in atm, tolerance 0.03.
Answer: 28.81 atm
P=V−nbnRT−V2an2=0.400−0.015250.500×28.735−0.1605.46×0.25=0.3847514.3675−8.531=37.342−8.531=28.811atm, i.e. 28.81atm.