NEET levelSingle correct optionDifficulty 1 of 3rg124
Assertion (A): The van der Waals constant a for NHX3 is greater than that for NX2. Reason (R): NHX3 molecules are held by hydrogen bonds in addition to dispersion forces. Choose the correct option.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
a for NHX3 is 4.17 and for NX2 is 1.39L2atmmol−2. The larger attraction in ammonia arises from hydrogen bonding and dipole-dipole forces that nitrogen lacks, so R explains A.