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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qc183

Regarding the tin sulphides in the analysis of group IIB, which statements are correct?

  1. ASnS is brown and SnS is yellow
  2. B dissolves in colourless ammonium sulphide as thiostannate
  3. CSnS dissolves in colourless ammonium sulphide without oxidation
  4. DYellow ammonium polysulphide oxidises SnS to a soluble thiostannate,

Answer: A, B, D

SnS (Sn(II)) is brown and (Sn(IV)) yellow. Only the acidic Sn(IV) sulphide forms the thiostannate with ; SnS is basic and does not dissolve in colourless , but the polysulphide in the yellow reagent oxidises Sn(II) to Sn(IV) so SnS dissolves. Hence 1, 2 and 4.
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More questions on Group I and group II cations (Pb, Cu, Bi, Cd, As, Sb, Sn)