JEE Main levelSingle correct optionDifficulty 2 of 3qc170
Assertion (A): PbX2+ can be found in both group I and group II of the cation scheme. Reason (R): PbClX2 is appreciably soluble in cold water and dilute HCl, so part of the lead stays in solution when group I is precipitated.
AA is false but R is true
BBoth A and R are true and R is the correct explanation of A
CA is true but R is false
DBoth A and R are true but R is not the correct explanation of A
Answer: B
PbClX2 has a fairly large solubility (about 10−2M), so the lead is only partly precipitated by dilute HCl. The remaining PbX2+ is later precipitated as black PbS by HX2S in group II. Both statements are true and R explains A.