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MolSynapse / Question bank / Qualitative Analysis: Cations / Group I and group II cations (Pb, Cu, Bi, Cd, As, Sb, Sn)
JEE Main levelSingle correct optionDifficulty 2 of 3qc170

Assertion (A): can be found in both group I and group II of the cation scheme. Reason (R): is appreciably soluble in cold water and dilute HCl, so part of the lead stays in solution when group I is precipitated.

  1. AA is false but R is true
  2. BBoth A and R are true and R is the correct explanation of A
  3. CA is true but R is false
  4. DBoth A and R are true but R is not the correct explanation of A

Answer: B

has a fairly large solubility (about ), so the lead is only partly precipitated by dilute HCl. The remaining is later precipitated as black PbS by in group II. Both statements are true and R explains A.
Practice Qualitative Analysis: Cations More on Group I and group II cations (Pb, Cu, Bi, Cd, As, Sb, Sn)

More questions on Group I and group II cations (Pb, Cu, Bi, Cd, As, Sb, Sn)