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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qc152

Which statements about magnesium ammonium phosphate, formed in the group VI test, are correct?

  1. AIt is precipitated only when and are present, i.e. in ammoniacal medium.
  2. BIt dissolves in dilute acetic acid and in mineral acids.
  3. CIt is a yellow solid.
  4. DStrong ignition converts it into magnesium pyrophosphate, .

Answer: A, B, D

The phosphate precipitates as the white crystalline salt only when ammonium ions and ammonia are available, and the salt is soluble in acids because phosphate is protonated. Ignition gives with loss of and water. The salt is white, not yellow.
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