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JEE Main levelOne or more correct optionsDifficulty 2 of 3qc142

Which of the following statements about the nickel dimethylglyoximate complex, , are correct?

  1. AThe complex is square planar with nickel in the state.
  2. BTwo intramolecular hydrogen bonds link the two ligands.
  3. CThe complex is paramagnetic with two unpaired electrons.
  4. DNickel is tetrahedrally coordinated through the oxygen atoms.

Answer: A, B

() with strong-field nitrogen donors forms a square planar, diamagnetic () complex in which each ligand binds through its two N atoms. The ligands are held together by two hydrogen bonds. So the statements about paramagnetism and tetrahedral O-coordination are wrong.
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