JEE Advanced levelSingle correct optionDifficulty 3 of 3qc094
Which statement correctly explains why AlX3+ is NOT detected as a sulphide when HX2S is passed through the ammoniacal solution (group IV step) containing it?
AAlX3+ is oxidised to AlX4+ by HX2S
BAlX2SX3 is completely hydrolysed, so white Al(OH)X3 is obtained, with release of HX2S
CAlX2SX3 is a yellow precipitate, so it cannot be mistaken for Al(OH)X3
DAlX2SX3 is amphoteric and dissolves in ammonia
Answer: B
AlX2SX3+6HX2O2Al(OH)X3+3HX2S goes to completion in water. Aluminium therefore appears as white gelatinous hydroxide, which is why it is placed in group III and why group III must be fully removed before group IV.