JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qa220
Which of the following observations with lead nitrate solution are correct?
ANaX2S gives a white precipitate of PbS
BNaX2SOX4 gives white PbSOX4 soluble in hot ammonium acetate
CConcentrated NaCl gives white PbClX2 that dissolves in hot water
DKI gives bright yellow PbIX2 that dissolves on heating and reappears as golden spangles on cooling
Answer: B, C, D
PbClX2 is sparingly soluble in cold but soluble in hot water, and PbIX2 crystallises as golden spangles. PbSOX4 dissolves in ammonium acetate through formation of a lead acetate complex. PbS is black, not white.