JEE Main levelSingle correct optionDifficulty 2 of 3qa096
A yellow precipitate formed on adding Pb(NOX3)X2 to a colourless solution dissolves on boiling, and golden-yellow spangles separate on cooling. The precipitate is
APbCrOX4
BPbIX2
CAgI
DCdS
Answer: B
PbIX2 is considerably more soluble in hot water and recrystallises as golden spangles on cooling. The other yellow solids (PbCrOX4, AgI, CdS) do not dissolve in boiling water. The test confirms iodide.