JEE Advanced levelSingle correct optionDifficulty 3 of 3qa202
A solution contains 0.0100 mol NaX2SOX4 and 0.0100 mol NaX3POX4. Excess BaClX2 is added at neutral pH, forming both barium salts completely, and then excess dilute HCl is added. The mass of the precipitate remaining is (Ba 137, S 32, P 31, O 16)
A2.33 g
B5.34 g
C3.01 g
D1.17 g
Answer: A
BaSOX4 (233gmol−1) is 0.0100 mol, i.e. 2.33 g. BaX3(POX4)X2 (601) would be 0.00500 mol, 3.01 g, so the initial precipitate is 5.34 g. In excess dilute HCl the phosphate dissolves and only BaSOX4, 2.33 g, remains.