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JEE Advanced levelSingle correct optionDifficulty 3 of 3qa202

A solution contains 0.0100 mol and 0.0100 mol . Excess is added at neutral pH, forming both barium salts completely, and then excess dilute is added. The mass of the precipitate remaining is (Ba 137, S 32, P 31, O 16)

  1. A2.33 g
  2. B5.34 g
  3. C3.01 g
  4. D1.17 g

Answer: A

() is 0.0100 mol, i.e. 2.33 g. (601) would be 0.00500 mol, 3.01 g, so the initial precipitate is 5.34 g. In excess dilute the phosphate dissolves and only , 2.33 g, remains.
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