JEE Advanced levelSingle correct optionDifficulty 3 of 3qa201
Assertion (A): The green flame test for borate is performed with ethanol (or methanol) and conc. HX2SOX4, not with dilute acid.
Reason (R): Formation of the volatile borate ester from boric acid and the alcohol is a condensation that needs a dehydrating medium.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
B(OH)X3+3CHX3OHB(OCHX3)X3+3HX2O is an esterification equilibrium, which is driven forward by the water-absorbing conc. HX2SOX4. Dilute acid would supply water and shift it back. Both A and R are true and R explains A.