JEE Main levelOne or more correct optionsDifficulty 2 of 3qa139
Select all correct statements about the oxalate ion in qualitative analysis.
AIt decolourises hot, acidified KMnOX4 solution.
BBoth gases evolved with concentrated HX2SOX4 turn lime water milky.
CWarming its salt with concentrated HX2SOX4 gives CO and COX2 in equal moles.
DWith aqueous CaClX2 it gives a white precipitate that is insoluble in acetic acid but dissolves in dilute HCl.
Answer: A, C, D
2MnOX4X−+5CX2OX4X2−+16HX+2MnX2++10COX2+8HX2O decolourises the permanganate. CaCX2OX4 is white, insoluble in acetic acid and soluble in strong acid. Conc. HX2SOX4 gives CO and COX2 in a 1:1 ratio, but CO does not turn lime water milky, so the last statement is false.