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JEE Main levelOne or more correct optionsDifficulty 2 of 3qa084

Which of the following ions interfere with the brown ring test for nitrate (that is, give a brown ring or a coloured vapour/layer that masks it) if not removed beforehand? One or more options may be correct.

  1. A
  2. B
  3. C
  4. D

Answer: B, C, D

Nitrite gives the brown nitrosyl complex itself. Bromide and iodide are oxidised by concentrated to brown and violet/brown , which mask the ring. Chloride gives only colourless HCl and does not interfere. Correct: first three.
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