JEE Main levelSingle correct optionDifficulty 2 of 3qa082
Assertion (A): Mercury(II) chloride does not give the chromyl chloride test.
Reason (R): HgClX2 is a covalent compound and does not furnish free ClX− ions to the reaction mixture.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
Both statements are true. Formation of CrOX2ClX2 requires free chloride ions reacting with chromic acid species in the acid medium, and HgClX2 is largely molecular. R therefore explains A.