JEE Main levelOne or more correct optionsDifficulty 2 of 3qa064
Which of the following statements about borate analysis are correct? One or more options may be correct.
ABoric acid is a tribasic Bronsted acid giving BOX3X3− in water.
BVolatile B(OCX2HX5)X3 is formed when borate is heated with ethanol and concentrated HX2SOX4.
CAn aqueous solution of borax is alkaline.
DBoron in B(OCX2HX5)X3 is sp2 hybridised.
Answer: B, C, D
The ester B(OCX2HX5)X3 is volatile and trigonal planar (sp2 B). Borax hydrolyses to HX3BOX3 and OHX−, so its solution is alkaline. Boric acid is not tribasic; it is a weak monobasic Lewis acid, B(OH)X3+HX2O[B(OH)X4]X−+HX+. Correct: first, second and fourth.