JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qa036
Which of the following statements about the thiosulphate ion are correct?
AWith dilute HCl it gives SOX2 and a turbidity of sulphur.
BIt reduces iodine to iodide, being oxidised to tetrathionate.
CWith excess AgNOX3 it gives a white precipitate that turns black on standing.
DWith alkaline sodium nitroprusside it gives the purple NaX4[Fe(CN)X5NOS], like SX2−.
Answer: A, B, C
Statement 1 follows from SX2OX3X2−+2HX+S+SOX2+HX2O. Statement 2: 2SX2OX3X2−+IX2SX4OX6X2−+2IX−. Statement 3: AgX2SX2OX3 hydrolyses to black AgX2S. Statement 4 describes the test for sulphide, not thiosulphate.