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JEE Main levelSingle correct optionDifficulty 2 of 3pl236

The two compounds shown react together to give a polymer used as a fibre. Which description of the polymerisation is correct?

  1. AChain-growth addition with no by-product
  2. BStep-growth condensation using two different monomers, with water eliminated
  3. CChain-growth addition using one monomer
  4. DStep-growth condensation using one monomer, with HCl eliminated

Answer: B

Hexane-1,6-diamine and hexanedioic (adipic) acid have two reactive groups each. They link through amide bonds with elimination of water, so growth is step-growth and the product is nylon 6,6, made of two different monomers. A chain-growth radical route needs C=C bonds, which neither compound has, and no HCl is involved because no acid chloride is used.
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