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JEE Advanced levelSingle correct optionDifficulty 3 of 3pl072

Equimolar hexamethylenediamine and adipic acid are polymerised until of the functional groups have reacted. Use for the number-average number of monomer molecules per chain, and take the repeat unit of nylon 6,6 (one diamine residue plus one diacid residue) as 226 g/mol; neglect end groups. The number-average molar mass is

  1. A
  2. B
  3. C
  4. D

Answer: A

monomer molecules per chain. Each repeat unit contains two monomer residues, so a chain has 100 repeat units, giving . Using 200 repeat units would double-count.
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