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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pl069

For step-growth polymerisation of an equimolar mixture of a diamine and a diacid, use the Carothers equation , where is the fraction of functional groups reacted. Which statements are correct?

  1. AAt the number-average number of monomer units per chain is 50.
  2. BA radical initiator is needed to start each chain.
  3. CMonomers are used up early, and high molar mass chains appear only when is very close to 1.
  4. DRemoving the small by-product (water) from the mixture helps push the reaction to high .

Answer: A, C, D

With , . In step growth any two molecules bearing the right end groups can react, so oligomers form first and long chains need near 1; removing water drives the equilibrium. No initiator is required, so option 2 is wrong.
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