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JEE Advanced levelSingle correct optionDifficulty 3 of 3pl026

In a free radical polymerisation the rate of polymerisation is and the average degree of polymerisation is proportional to , where I is the initiator. At fixed monomer concentration and temperature, the initiator concentration is made four times larger. Then

  1. A becomes four times and the average degree of polymerisation becomes one quarter
  2. B becomes twice and the average degree of polymerisation becomes half
  3. C becomes twice and the average degree of polymerisation becomes twice
  4. D becomes half and the average degree of polymerisation becomes twice

Answer: B

With , . is multiplied by 2 and the degree of polymerisation by : more radicals mean faster reaction but shorter chains.
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