JEE Main levelSingle correct optionDifficulty 2 of 3pl025
Phenol-formaldehyde resin is made in two stages, novolac and then bakelite. Which statement about novolac is correct?
AIt is a linear, fusible, low molar mass polymer made with phenol in excess under acid catalysis, and heating it with hexamethylenetetramine gives cross-linked bakelite
BIt is the final infusible cross-linked form of the resin
CIt is made with excess methanal under basic catalysis and already carries many −CHX2OH groups
DIt is a condensation polymer of phenol with phthalic anhydride
Answer: A
Excess phenol with acid catalyst gives linear novolac; the base-catalysed, methanal-rich product with −CHX2OH groups is the resole. Novolac is cross-linked into bakelite by hexamethylenetetramine on heating.