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JEE Advanced levelSingle correct optionDifficulty 3 of 3pt189

Excess aqueous is added to a small amount of solution. The white precipitate formed is . Which of the following describes the oxidation-state changes?

  1. ASn: ; Hg:
  2. BSn: ; Hg:
  3. CSn: ; Hg:
  4. DSn: ; Hg:

Answer: A

Tin(II) is a good reductant because the inert pair effect is weaker for tin than for lead, so is the more stable state. It reduces Hg(II) to Hg(I) in (white) when is in excess; with excess the reduction would continue to grey metallic Hg. So Sn goes and Hg goes .
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