JEE Main levelSingle correct optionDifficulty 2 of 3pt186
According to the Mulliken scale, electronegativity is proportional to the average of ionisation enthalpy and electron gain enthalpy (magnitude). Element X has IE=1140 and ∣ΔegH∣=330 kJ/mol; element Y has IE=900 and ∣ΔegH∣=120 kJ/mol. The ratio χX/χY is
A1.44
B1.27
C0.69
D1.67
Answer: A
The Mulliken value is (IE+EA)/2, giving 735 kJ/mol for X and 510 kJ/mol for Y. The ratio is 735/510=1.44. The value 1.27 comes from using only the ionisation enthalpies (1140/900) and 0.69 is the inverted ratio.