JEE Advanced levelSingle correct optionDifficulty 3 of 3pt148
Use ΔiH1(Na)=496 and ΔiH2(Mg)=1451kJmol−1. The enthalpy change for Na(g)+MgX2+(g)→NaX+(g)+MgX+(g) is
A−955kJmol−1
B+955kJmol−1
C+1947kJmol−1
D−242kJmol−1
Answer: A
The reaction is the sum of ionising Na (+496) and the reverse of the second ionisation of Mg (-1451, because MgX2+ gains an electron to form MgX+). Net = 496 - 1451 = -955 kJ/mol, exothermic.