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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pt098

Use the following rule set. Slater's rules: write the configuration in groups For an electron in an or group, every other electron in the same group contributes ( for the group), every electron in the shell contributes , every electron in the or lower shells contributes , and electrons in groups to the right contribute . For an electron in an or group, every other electron in the same group contributes , every electron in all groups to its left contributes , and groups to the right contribute . . The valence-electron values are evaluated for the third-period elements Na to Cl, each with the configuration . Which statements are correct?

  1. AThe of aluminium is smaller than that of magnesium.
  2. BThe of sulfur is 5.45.
  3. CThe ratio is 2.77.
  4. D increases by 0.65 for every unit increase in atomic number from Na to Cl.

Answer: B, C, D

Each added electron to the 3s,3p group changes by while rises by , so rises by per element. Values: Na 2.20, Mg 2.85, Al 3.50, S 5.45, Cl 6.10. . Al () is larger than Mg ().
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