JEE Advanced levelSingle correct optionDifficulty 3 of 3pt091
Use the following rule set. Slater's rules: write the configuration in groups (1s)(2s,2p)(3s,3p)(3d)(4s,4p)(4d)(4f)(5s,5p)… For an electron in an ns or np group, every other electron in the same group contributes 0.35 (0.30 for the 1s group), every electron in the (n−1) shell contributes 0.85, every electron in the (n−2) or lower shells contributes 1.00, and electrons in groups to the right contribute 0. For an electron in an nd or nf group, every other electron in the same group contributes 0.35, every electron in all groups to its left contributes 1.00, and groups to the right contribute 0. Z∗=Z−S. The Slater orbital energy is E=−13.6(Z∗)2/(n∗)2eV with n∗=1 for n=1. The magnitude of the energy of a 1s electron in LiX+ (Z=3, configuration 1s2) is:
A122.4eV
B95.5eV
C99.1eV
D62.9eV
Answer: C
For a 1s electron S=0.30, so Z∗=2.70. ∣E∣=13.6×(2.70)2=99.1eV.