JEE Main levelSingle correct optionDifficulty 2 of 3pt081
The metallic radius of aluminium is 143pm and that of gallium is 135pm, although gallium lies one period below. This is best explained by:
Agallium having fewer electron shells than aluminium
Bpoor shielding by the ten 3d electrons inserted before gallium, giving a higher Zeff than simple extrapolation predicts
Cthe lanthanoid contraction, which acts on all elements of Group 13
Dthe inert pair effect making gallium use fewer bonding electrons
Answer: B
Between Al and Ga the 3d subshell is filled. These d electrons shield the nuclear charge ineffectively, so Zeff on the 4p electron is high and the size increase from the extra shell is almost cancelled.