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JEE Advanced levelSingle correct optionDifficulty 3 of 3ph180

Bond dissociation enthalpies (): 159, 243, 193, 151. Consider: (i) the order is ; (ii) the electron gain enthalpy of F is more negative than that of Cl; (iii) HF is the weakest of the hydrohalic acids in water; (iv) has the lowest bond dissociation enthalpy among the halogens; (v) the colour of the halogens deepens from to . The number of correct statements is

  1. A3
  2. B2
  3. C4
  4. D5

Answer: A

(i) is true from the data: 243 > 193 > 159 > 151. (ii) is false because Cl () is more negative than F (). (iii) is true, as HF is a weak acid while HCl, HBr and HI are strong. (iv) is false because has the lowest value (151). (v) is true: pale yellow, greenish yellow, red-brown, violet. Statements (i), (iii) and (v) are correct, so the count is 3.
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