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The F-F bond dissociation enthalpy () is lower than that of Cl-Cl (). The main reason is

  1. Athe F-F bond is ionic in nature
  2. BF has vacant d orbitals that weaken the bond
  3. Cthe F atom is larger than the Cl atom
  4. Dstrong repulsion between the lone pairs on the two small, closely bound F atoms

Answer: D

F atoms are very small, so the bond is short and the nonbonding lone pairs on the two atoms repel each other strongly, weakening the F-F bond. F is smaller (not larger) than Cl and has no d orbitals in its valence shell. The bond is covalent.
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