JEE Main levelSingle correct optionDifficulty 2 of 3ph123
Which set of conditions is used to prepare XeFX6 from the elements?
AXe : FX2 = 1 : 20, 873 K, 1 bar
BXe : FX2 = 1 : 20, 573 K, 60-70 bar
CXe : FX2 = 1 : 5, 873 K, 7 bar
DExcess Xe, 673 K, 1 bar
Answer: B
Forming the highest fluoride needs a large excess of fluorine (1:20), a lower temperature (573 K) and a high pressure (60-70 bar). The 1:5 ratio at 873 K and 7 bar gives XeF4, and excess Xe at 673 K and 1 bar gives XeF2.