JEE Main levelOne or more correct optionsDifficulty 2 of 3ph099
Which of the following reactions of chlorine are correctly stated?
AMethane reacts with ClX2 in light by free radical substitution.
BClX2 displaces FX− from NaF to give FX2.
CDry slaked lime absorbs ClX2 to give bleaching powder, CaOClX2.
DHX2S is oxidised by ClX2 to sulphur.
Answer: A, C, D
Ca(OH)X2+ClX2CaOClX2+HX2O; HX2S+ClX22HCl+S; CHX4+ClX2CHX3Cl+HCl under light. Fluorine is a stronger oxidant than chlorine (E of FX2/FX− is larger), so ClX2 cannot displace fluoride.