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p-Block Elements: Groups 17 and 18
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Trends in halogens
JEE Advanced level
Single correct option
Difficulty 3 of 3
ph036
Given
E
∘
(
Cl
X
2
/
Cl
X
−
)
=
1.36
V and
E
∘
(
Br
X
2
/
Br
X
−
)
=
1.09
V, the standard Gibbs energy change for
Cl
X
2
+
2
Br
X
−
2
Cl
X
−
+
Br
X
2
at 298 K (F = 96500 C/mol) is
A
−
26.1
kJ
mo
l
−
1
B
−
104.2
kJ
mo
l
−
1
C
−
52.1
kJ
mo
l
−
1
D
+
52.1
kJ
mo
l
−
1
Answer: C
E
ce
ll
∘
=
1.36
−
1.09
=
0.27
V and n = 2.
Δ
G
∘
=
−
n
F
E
∘
=
−
2
×
96500
×
0.27
=
−
52110
J, which is
−
52.1
kJ/mol.
Practice p-Block Elements: Groups 17 and 18
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