JEE Main levelSingle correct optionDifficulty 2 of 3ph014
The correct order of bond dissociation enthalpy of the halogen molecules is
AFX2>ClX2>BrX2>IX2
BIX2>BrX2>ClX2>FX2
CClX2>BrX2>FX2>IX2
DClX2>FX2>BrX2>IX2
Answer: C
The bond enthalpies are about Cl2 242.6, Br2 192.8, F2 158.8 and I2 151.1 kJ/mol. The F-F bond is anomalously weak because of lone-pair repulsion, so F2 falls below Cl2 and Br2.