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JEE Main levelSingle correct optionDifficulty 2 of 3ph014

The correct order of bond dissociation enthalpy of the halogen molecules is

  1. A
  2. B
  3. C
  4. D

Answer: C

The bond enthalpies are about Cl2 242.6, Br2 192.8, F2 158.8 and I2 151.1 kJ/mol. The F-F bond is anomalously weak because of lone-pair repulsion, so F2 falls below Cl2 and Br2.
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